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By Schoder R.V., Horrigan V.C.

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Biol. , 2001, 30, 170. J. Pla´tenı´ k, P. Stopka, M. Vejrazˇ ka and S. Sˇtı´ pek, Free Radic. , 2001, 34, 445. V. C. Culotta, J. Biol. , 2000, 275, 25057. M. Mylonas, G. Malandrinos, J. Plakatouras, N. S. Kasprzak, . Krezel and W. Bal, Chem. Res. , 2001, 14, 1177. N. Shishido, K. Nakayama, A. Takazawa, T. Ohyama and M. Nakamura, Arch. Biochem. , 2001, 387, 216. -X. Liu, K. A. Y. G. P. J. R. E. Kagan, Biochem. , 2001, 354, 397. R. Basosi, N. D’Amelio, E. Gaggelli, R. Pogni and G. Valensin, J. Chem.

Egashira and Y. , 2001, 68, 1807. -Z. Zhu, Chem. Res. , 2001, 14, 222. C. Yuan, M. E.

151 Similar spectra were observed following incubation of the aldehyde with respiring submitochondrial particles. 151 Bile samples provided spectra consisting of signals from POBN/·CH3 and a second species. The generation of POBN/·CH3 was confirmed using 13 C-labelled acetaldehyde, but the second species did not display 13C-coupling and was, therefore, assigned to a trapped radical centred on an endogenous molecule. The absence of a signal from POBN/·COCH3 was attributed to its instability. The authors proposed that, in addition to undergoing H-abstraction by the ·OH radical to ·COCH3 (which yields ·CH3 upon -scission), acetaldehyde may be oxidised through a mechanism involving nucleophilic attack by either HOO9 or ONOO9.

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